First Name: Andrew S.Last Name: BorovikPublications: YearPublication 1984"Synthesis of a phenoxy-bridged copper(I) dimer and its reaction with dioxygen: implications for the reversible binding of O2 by hemocyanin" in Journal of the Chemical Society, Chemical Communications 1986"Synthesis of new tripod ligands providing a phenolate donor. Structure of a stable monomeric copper(I) phenolate complex" in Inorganic Chemistry 1986"Luminescence behavior of copper(I)-imidazole complexes. A spectroscopic model for the carbonyl derivative of hemocyanin" in Journal of the American Chemical Society 1986"Ultraviolet absorption and resonance Raman spectra of copper(I) complexes" in Journal of the American Chemical Society 1987"Absorption, emission, and photophysical properties of copper(I) pyrazole complexes and their carbonyl adducts" in Inorganic Chemistry 1987"Synthesis, structure, and spectroscopic properties of an unusual copper(I) dimer having imidazole ligands. A model for the carbonyl derivative of hemocyanin and implications for the structure of deoxyhemocyanin" in Journal of the American Chemical Society 1987"Models for iron-oxo proteins: a mixed valence iron(II)-iron(III) complex" in Journal of the American Chemical Society 1988"Models for the iron(II)iron(III) and iron(II)iron(II) forms of iron-oxo proteins" in Journal of the American Chemical Society 1988"Heterobimetallic complexes with (.mu.-phenoxo)bis(.mu.-carboxylato) cores" in Journal of the American Chemical Society 1989"Models for iron-oxo proteins. Structures and properties of FeIIFeIII, ZnIIFeIII, and FeIIGaIII complexes with (.mu.-phenoxo)bis(.mu.-carboxylato)dimetal cores" in Journal of the American Chemical Society 1989"Characterizations Of Metal Ions In Biological Systems" in Heavy Metal Tolerance in Plants: Evolutionary Aspects 1990"Models for diferrous forms of iron-oxo proteins. Structure and properties of [Fe2BPMP(O2CR)2]BPh4 complexes" in Journal of the American Chemical Society 1993"Amidate ligands for the oxovanadium(IV) cation: design, synthesis, structure, and spectroscopic and electrochemical properties" in Inorganic Chemistry 1995"Synthesis and characterization of a trigonal monopyramidal nickel(II) complex" in Journcal of the Chemical Society, Chemical Communications 1995"Rezeptoren für Oxometall-Kationen: Koordination an das Dioxoosmium(VI)-Kation über verschiedenartige bindende Wechselwirkungen" in Angewandte Chemie 1995"Metal Oxo Cation Receptors: Multimode Coordination to the Dioxoosmium(VI) Cation" in Angewandte Chemie 1995"Metallohelices: Effects of Weak Interactions on Helical Morphology" in Inorganic Chemistry 1995"Metallo-Network Polymers: Reversible CO Binding to an Immobilized Copper(I) Complex" in Journal of the American Chemical Society 1996"Synthesis and Structure of Helical Supramolecular Arrays" in Journal of the American Chemical Society 1996"Synthesis and Structure of a Trigonal Monopyramidal Fe(II) Complex and Its Paramagnetic Carbon Monoxide Derivative" in Journal of the American Chemical Society 1997"Review of Perspectives in Supramolecular Chemistry, Volume 1. The Lock and Key Principle. The State of the Arts - 100 Years on by Jean-Paul Behr" in Journal of the American Chemical Society 1997"C3-Symmetric Chiral Amidate Complexes: Effects of Ligand Binding on Cavity Structure" in Inorganic Chemistry 1997"Synthesis and structure of a MnIII(OH) complex generated from dioxygen" in Chemical Communications 1998"Structure and Physical Properties of Trigonal Monopyramidal Iron(II), Cobalt(II), Nickel(II), and Zinc(II) Complexes" in Inorganic Chemistry 1998"Syntheses and Structures of Nickel(II) and Copper(II) Complexes of 2,6-Bis[(2-acetylphenyl)carbamoyl]pyridine: Effects of Molecular Structure on Crystal Lattice Architecture" in Inorganic Chemistry 1998"The use of C3-symmetric tripodal ligands in crystal engineering" in Coordination Chemistry Reviews 1998"Synthesis and structure of chiral 2,6-bis[(2-carbamoylphenyl)carbamoyl]pyridine ligands" in Tetrahedron Letters 1998"Designing Metal Complexes in Porous Organic Hosts" in Molecular and Ionic Recognition with Imprinted Polymers 1998"Dioxygen binding to immobilized CoII complexes in porous organic hosts: evidence for site isolation" in Chemical Communications 1999"Metallionen in einseitig von H-Brücken begrenzten Hohlräumen: ein Redoxpaar koordinativ ungesättigter paramagnetischer Co-OH-Komplexe" in Angewandte Chemie 1999"Structure and Magnetic Properties of Trigonal Bipyramidal Iron Nitrosyl Complexes" in Inorganic Chemistry 1999"Hydrogen bonded antiparallel β-strand motifs promoted by 2,6-bis(carbamoylpeptide)pyridine" in Chemical Communications 2000"Hydrogen Bonding in Metal Oxo Complexes: Synthesis and Structure of a Monomeric Manganese(III)−Oxo Complex and Its Hydroxo Analogue" in Journal of the American Chemical Society 2000"O2 Activation by Nonheme Iron Complexes: A Monomeric Fe(III)-Oxo Complex Derived from O2" in Science 2000"Design, Synthesis, and Characterization of Templated Metal Sites in Porous Organic Hosts: Application to Reversible Dioxygen Binding" in Journal of the American Chemical Society 2001"Immobilized Metal Complexes in Porous Organic Hosts: Development of a Material for the Selective and Reversible Binding of Nitric Oxide" in Journal of the American Chemical Society 2001"Surface grafting of cobalt complexes on polymeric supports: Evidence for site isolation and applications to reversible dioxygen binding" in Journal of Polymer Science Part A: Polymer Chemistry 2001'Hydrogen-Bonding Cavities about Metal Ions: Synthesis, Structure, and Physical Properties for a Series of Monomeric M−OH Complexes Derived from Water" in Inorganic Chemistry 2001"Probing the Structure of Immobilized Metal Sites in Porous Organic Hosts by X-ray Absorption Spectroscopy" in Chemistry of Materials 2002"The Use of Non-Covalent Interactions in the Assembly of Metal/Organic Supramolecular Arrays" in Comments on Inorganic Chemistry 2002"Isolation of Monomeric MnIII/II−OH and MnIII−O Complexes from Water: Evaluation of O−H Bond Dissociation Energies" in Journal of the American Chemical Society 2002"C2-Symmetric ligands containing hydrogen bond donors: synthesis and properties of Cu(ii) complexes of 2,6-bis[N,N′-(2-carboxamidophenyl)carbamoyl]pyridine" in Journal of the Chemical Society, Dalton Transactions 2002"Synthesis and Characterization of Completely Delocalized Mixed-Valent Dicopper Complexes" in Inorganic Chemistry 2002"A bidentate ligand with appended hydrogen bond donors:: synthesis and structure of four-coordinate metal complexes with bis[(tert-butyl)aminocarbonyl]-1,2-diaminoethane" in Inorganica Chimica Acta 2003"Hydrogen Bonds around M(μ-O)2M Rhombs: Stabilizing a {CoIII(μ-O)2CoIII} Complex at Room Temperature" in Angewandte Chemie 2003"Metal ion mediated activation of dioxygen: Formation of non-heme complexes with terminal oxo and hydroxo ligands" in Journal of Inorganic Biochemistry 2003"Immobilization of a Europium Salen Complex within Porous Organic Hosts: Modulation of Luminescence Properties in Different Chemical Environments" in Chemistry of Materials 2003"Monomeric MnIII/II and FeIII/II Complexes with Terminal Hydroxo and Oxo Ligands: Probing Reactivity via O−H Bond Dissociation Energies" in Journal of the American Chemical Society 2003"Development of bio-inspired chelates with hydrogen bond donors: synthesis and structure of monomeric metal acetate complexes with intramolecular hydrogen bonds" in Dalton Transactions 2004"Utilization of Hydrogen Bonds To Stabilize M−O(H) Units: Synthesis and Properties of Monomeric Iron and Manganese Complexes with Terminal Oxo and Hydroxo Ligands" in Journal of the American Chemical Society 2004"Synthetic Creatinine Receptor: Imprinting of a Lewis Acidic Zinc(II)cyclen Binding Site to Shape Its Molecular Recognition Selectivity" in Journal of the American Chemical Society 2004"Application of CO2-expanded solvents in heterogeneous catalysis: a case study" in Applied Catalysis B: Environmental 2004"Light-Activated Transfer of Nitric Oxide from a Porous Material" in Angewandte Chemie 2004"Predetermined Helical Chirality in Octahedral Complexes with a Novel Pentadentate C2-Symmetrical Chiral Bis(oxazoline) Ligand" in Advanced Synthesis & Catalysis 2004"Chalcogens as Terminal Ligands to Iron: Synthesis and Structure of Complexes with FeIII−S and FeIII−Se Motifs" in Journal of the American Chemical Society 2005"Bioinspired Hydrogen Bond Motifs in Ligand Design: The Role of Noncovalent Interactions in Metal Ion Mediated Activation of Dioxygen" in Accounts of Chemical Research 2005"Development of Porous Materials for Heterogeneous Catalysis: Kinetic Resolution of Epoxides" in ChemInform 2005"Bioinspired Hydrogen Bond Motifs in Ligand Design: The Role of Noncovalent Interactions in Metal Ion Mediated Activation of Dioxygen" in ChemInform 2005"Nanoparticulate Metal Complexes Prepared with Compressed Carbon Dioxide: Correlation of Particle Morphology with Precursor Structure" in Journal of the American Chemical Society 2005"Preparation of Iron Amido Complexes via Putative Fe(IV) Imido Intermediates" in Journal of the American Chemical Society 2005"Confinement of Metal Complexes within Porous Hosts: Development of Functional Materials for Gas Binding and Catalysis" in Accounts of Chemical Research 2006"Confinement of Metal Complexes within Porous Hosts: Development of Functional Materials for Gas Binding and Catalysis" in ChemInform 2006"Modification of immobilized metal complexes toward the design and synthesis of functional materials for nitric oxide delivery" in Journal of Polymer Science Part A: Polymer Chemistry 2006"Pyrazolate-Bridging Dinucleating Ligands Containing Hydrogen-Bond Donors: Synthesis and Structure of Their Cobalt Analogues" in Inorganic Chemistry 2006"Preparation and Properties of a Monomeric MnIV−Oxo Complex" in Journal of the American Chemical Society 2006"X-ray Absorption Spectroscopy and Density Functional Theory Studies of [(H3buea)FeIII-X]n- (X = S2-, O2-, OH-): Comparison of Bonding and Hydrogen Bonding in Oxo and Sulfido Complexes" in Journal of the American Chemical Society 2006"Characterization of the Particulate Methane Monooxygenase Metal Centers in Multiple Redox States by X-ray Absorption Spectroscopy" in Inorganic Chemistry 2006"A Modular Approach toward Regulating the Secondary Coordination Sphere of Metal Ions: Differential Dioxygen Activation Assisted by Intramolecular Hydrogen Bonds" in Journal of the American Chemical Society 2006"Dioxygen Binding and Activation: Reactive Intermediates" in Activation of Small Molecules: Organometallic and Bioinorganic Perspectives 2006"Immobilized metal complexes in porous hosts: catalytic oxidation of substituted phenols in CO2 media" in Green Chemistry 2007"Correction - A Modular Approach toward Regulating the Secondary Coordination Sphere of Metal Ions: Differential Dioxygen Activation Assisted by Intramolecular Hydrogen Bonds" in Journal of the American Chemical Society 2007"Immobilized Metal Complexes in Porous Hosts: Catalytic Oxidation of Substituted Phenols in CO2 Media" in ChemInform 2007"Synthesis and structures of dimeric iron(III)-Oxo and -imido complexes containing intramolecular hydrogen bonds" in Inorganica Chimica Acta 2007"Acetonitrile Hydration and Ethyl Acetate Hydrolysis by Pyrazolate-Bridged Cobalt(II) Dimers Containing Hydrogen-Bond Donors" in Inorganic Chemistry 2008"Synthesis, Structure, and Physical Properties for a Series of Monomeric Iron(III) Hydroxo Complexes with Varying Hydrogen-Bond Networks" in Inorganic Chemistry 2008"A Monomeric MnIII−Peroxo Complex Derived Directly from Dioxygen" in Journal of the American Chemical Society 2008"Correlation between Active Center Structure and Enhanced Dioxygen Binding in Co(salen) Nanoparticles: Characterization by In Situ Infrared, Raman, and X-ray Absorption Spectroscopies" in The Journal of Physical Chemistry C 2008"Nitric Oxide Disproportionation at Mild Temperatures by a Nanoparticulate Cobalt(II) Complex" in Chemistry of Materials 2008"The effects of hydrogen bonds on metal-mediated O2 activation and related processes" in Chemical Communications 2009"Lessons from nature: unraveling biological C-H bond activation" in Current Opinion in Chemical Biology 2009"C−H Bond Cleavage with Reductants: Re-Investigating the Reactivity of Monomeric MnIII/IV−Oxo Complexes and the Role of Oxo Ligand Basicity" in Journal of the American Chemical Society 2009"Near-stoichiometric O2 binding on metal centers in Co(salen) nanoparticles" in AIChE Journal 2009"Green Methods for Processing and Utilizing Metal Complexes" in Gas-Expanded Liquids and Near-Critical Media 2009"A structure and reactivity analysis of monomeric Ni(ii)–hydroxo complexes prepared from water" in Dalton Transactions 2010"Role of the Secondary Coordination Sphere in Metal-Mediated Dioxygen Activation" in Inorganic Chemistry 2010"Formation, Structure, and EPR Detection of a High Spin FeIV—Oxo Species Derived from Either an FeIII—Oxo or FeIII—OH Complex" in Journal of the American Chemical Society 2010"Nickel(II) complexes stabilized by bis[N-(6-pivalamido-2-pyridylmethyl)]benzylamine: Synthesis and characterization of complexes stabilized by a hydrogen bonding network" in Inorganica Chimica Acta 2010"Utilizing tautomerization of 2-amino-oxazoline in hydrogen bonding tripodal ligands" in Chemical Communications 2011"Catalytic Reduction of Dioxygen to Water with a Monomeric Manganese Complex at Room Temperature" in Journal of the American Chemical Society 2011"The Effects of Redox-Inactive Metal Ions on the Activation of Dioxygen: Isolation and Characterization of a Heterobimetallic Complex Containing a MnIII–(μ-OH)–CaII Core" in Journal of the American Chemical Society 2011"Structural Diversity in Metal Complexes with a Dinucleating Ligand Containing Carboxyamidopyridyl Groups" in Inorganic Chemistry 2011"Role of metal–oxo complexes in the cleavage of C–H bonds" in Chemical Society Reviews 2012"Preparation and Properties of a Monomeric High-Spin MnV–Oxo Complex" in Journal of the American Chemical Society 2012"Electron Paramagnetic Resonance and Mössbauer Spectroscopy and Density Functional Theory Analysis of a High-Spin FeIV–Oxo Complex" in Journal of the American Chemical Society 2012"Assembly and Properties of Heterobimetallic CoII/III/CaII Complexes with Aquo and Hydroxo Ligands" in Journal of the American Chemical Society 2012"Preparation and structures of dinuclear complexes containing MII–OH centers" in Chemical Communications 2012"Preparation of monolithic superparamagnetic nanoparticle–polymer composites using a polymerizable acetylacetonate and magnetite nanoparticles" in Polymer Chemistry 2012"Synthesis, structure, and physical properties for a series of trigonal bipyramidal MII–Cl complexes with intramolecular hydrogen bonds" in Dalton Transactions 2013"Metal complexes with varying intramolecular hydrogen bonding networks" in Polyhedron 2013"Preparation and structural properties of InIII–OH complexes" in Polyhedron 2013"Unsymmetrical Bimetallic Complexes with MII–(μ-OH)–MIII Cores (MIIMIII = FeIIFeIII, MnIIFeIII, MnIIMnIII): Structural, Magnetic, and Redox Properties" in Inorganic Chemistry 2013"Characterization of Monomeric MnII/III/IV–Hydroxo Complexes from X- and Q-Band Dual Mode Electron Paramagnetic Resonance (EPR) Spectroscopy" in Inorganic Chemistry 2013"L-Edge X-ray Absorption Spectroscopy of Dilute Systems Relevant to Metalloproteins Using an X-ray Free-Electron Laser" in The Journal of Physical Chemistry Letters 2013"Water Oxidation Using a Cobalt Monolayer Prepared by Underpotential Deposition" in Langmuir 2013"Dichotomous Hydrogen Atom Transfer vs Proton-Coupled Electron Transfer During Activation of X–H Bonds (X = C, N, O) by Nonheme Iron–Oxo Complexes of Variable Basicity" in Journal of the American Chemical Society 2013"Heterobimetallic complexes with MIII-(μ-OH)-MII cores (MIII = Fe, Mn, Ga; MII = Ca, Sr, and Ba): structural, kinetic, and redox properties" in Chemical Science 2013"Deconstructing water oxidation" in Nature Chemistry 2014"Preparation and properties of an MnIV–hydroxide complex: proton and electron transfer at a mononuclear manganese site and its relationship to the oxygen evolving complex within photosystem II" in Chemical Science 2014"Iron(II) Complexes Supported by Sulfonamido Tripodal Ligands: Endogenous versus Exogenous Substrate Oxidation" in Inorganic Chemistry 2014"Synthesis, structure and reactivity of FeII/III–NH3 complexes bearing a tripodal sulfonamido ligand" in Chemical Communications 2015"Sulfonamido tripods: Tuning redox potentials via ligand modifications" in Polyhedron 2015"High-spin Mn–oxo complexes and their relevance to the oxygen-evolving complex within photosystem II" in Proceedings of the National Academy of Sciences 2015"Lessons from Nature: A Bio-Inspired Approach to Molecular Design" in Biochemistry 2015"Terminal Metal–Oxo Species with Unusual Spin States" in Spin States in Biochemistry and Inorganic Chemistry: Influence on Structure and Reactivity 2015"Molecular Designs for Controlling the Local Environments around Metal Ions" in Accounts of Chemical Research 2016"Modular Artificial Cupredoxins" in Journal of the American Chemical Society 2016"Reactivity of an FeIV-Oxo Complex with Protons and Oxidants" in Journal of the American Chemical Society 2016"X-ray absorption spectroscopy using a self-seeded soft X-ray free-electron laser" in Optics Express 2017"Modulating the Primary and Secondary Coordination Spheres within a Series of CoII—OH Complexes" in Inorganic Chemistry 2017"Terminal NiII−OH/−OH2 complexes in trigonal bipyramidal geometries derived from H2O" in Polyhedron 2017"Models for Unsymmetrical Active Sites in Metalloproteins: Structural, Redox, and Magnetic Properties of Bimetallic Complexes with MII-(μ-OH)-FeIII Cores" in Inorganic Chemistry 2017"Peroxide Activation Regulated by Hydrogen Bonds within Artificial Cu Proteins" in Journal of the American Chemical Society 2017"Soft x-ray absorption spectroscopy of metalloproteins and high-valent metal-complexes at room temperature using free-electron lasers" Structural Dynamics 2018"Artificial Metalloproteins Containing Co4O4 Cubane Active Sites" in Journal of the American Chemical Society 2018"Mononuclear complexes of a tridentate redox-active ligand with sulfonamido groups: structure, properties, and reactivity" in Chemical Science 2018"Manganese–Hydroxido Complexes Supported by a Urea/Phosphinic Amide Tripodal Ligand" in Inorganic Chemistry 2018"Coordination chemistry within a protein host: regulation of the secondary coordination sphere" in Chemical Communications 2018"Modular bimetallic complexes with a sulfonamido-based ligand" in Dalton Transactions 2018"Probing Hydrogen Bonding Interactions to Iron-Oxido/Hydroxido Units by 57Fe Nuclear Resonance Vibrational Spectroscopy" in Angewandte Chemie International Edition 2019"Preface to the special issue in honor of Professor Rabindranath Mukherjee on the occasion of his 65th birthday" in Inorganica Chimica Acta 2019"Analysis of the Puzzling Exchange-Coupling Constants in a Series of Heterobimetallic Complexes" in Inorganic Chemistry 2019"Regulating the Basicity of Metal–Oxido Complexes with a Single Hydrogen Bond and Its Effect on C–H Bond Cleavage" in Journal of the American Chemical Society 2019"Stabilizing a NiII-aqua complex via intramolecular hydrogen bonds: Synthesis, structure, and redox properties" in Inorganica Chimica Acta 2020"Artificial Iron Proteins: Modeling the Active Sites in Non-Heme Dioxygenases" in Inorganic Chemistry 2020"Effects of Non-covalent Interactions on High-spin Fe(IV)–oxido Complexes" in Journal of the American Chemical Society 2021"Artificial Metalloproteins with Dinuclear Iron–Hydroxido Centers" in Journal of the American Chemical Society 2021"C–H Bond Cleavage by Bioinspired Nonheme Metal Complexes" in Inorganic Chemistry 2021"Semiempirical method for examining asynchronicity in metal–oxido-mediated C–H bond activation" in Proceedings of the National Academy of Sciences 2021"Stepwise assembly of heterobimetallic complexes: synthesis, structure, and physical properties" in Dalton Transactions 2021"Investigation of iron–ammine and amido complexes within a C3-symmetrical phosphinic amido tripodal ligand" in Dalton Transactions 2022"Bioinspired Di-Fe Complexes: Correlating Structure and Proton Transfer over Four Oxidation States" in Journal of the American Chemical Society 2022"Artificial Metalloproteins: At the Interface between Biology and Chemistry" in JACS Au 2023"In Support of Early-Career Researchers" in Inorganic Chemistry 2023"Selective C–H Bond Cleavage with a High-Spin FeIV–Oxido Complex" in Molecules 2023"X-ray Spectroscopic Study of the Electronic Structure of a Trigonal High-Spin Fe(IV)═O Complex Modeling Non-Heme Enzyme Intermediates and Their Reactivity" in Journal of the American Chemical Society 2023"Modulation of the Bonding between Copper and a Redox-Active Ligand by Hydrogen Bonds and Its Effect on Electronic Coupling and Spin States" in Journal of the American Chemical Society 2023"The role of basicity in selective C–H bond activation by transition metal-oxidos" in Dalton Transactions 2024"Accessing a synthetic FeIIIMnIV core to model biological heterobimetallic active sites" in Chemical Science 2024"Synthesis, characterization and reactivity of a Mn(III)–hydroxido complex as a biomimetic model for lipoxygenase" in Journal of Inorganic Biochemistry 2025"Selective oxidation of active site aromatic residues in engineered Cu proteins" in Chemical Science 2025"Proton-Induced Switching of Paramagnetism: Reversible Conversion between a Low and High Spin CoIII Center within a Heterobimetallic Core" in Journal of the American Chemical Society